That liquid beneficial bacteria stuff STILL requires the tank to cycle. As you noticed you are getting ammonia and nitrate which are extremely toxic to any fish. Discus being super sensitive I don't think it was a good idea to put them through a mini cycle. Especially with how expensive they can be.
I agree with everything the above said with one addition. I think you should increase your WC to 50-80% daily.
I let my nitrates get to 20ppm and two of my discus turned black and started breathing really heavy. All because they were used to <5. These guys are sensitive.