Anerobic bacteria excrete an assortment of toxic gasses...most of which are sulfide based. I go to great lengths to keep them out of my tank.
Denitrifying bacteria do NOT use DOC's to oxidize nitrate. DOC= Dissolved organic carbon... carbon, its an element on the periodic table that is distinctively missing from the formulas for ammonia (NH4) nitrite (No2-) and nitrate (No3-). The most common reaction for denitrification turns nitrate into Nitrogen gas and water. No carbon involved. The 10 spare electrons in the formula typically come from organic matter (carbon based substances) that are getting reduced. Notice I said reduced, not removed. Yes these bacteria are mostly heterotrophic, but their wastes are still carbon based and thus still DOC's, carbon dioxide is the most common one.
2NO3- + 10e- + 12H+ → N2 + 6H2O
A major flaw in your theory is that these things require anerobic conditions. Your water has DO in it. So you have to get these little bacteria guys water containing nitrates sufficiently to keep them alive and denitrifying with out getting them water that contains oxygen. Good luck with that part.
Futher adding to the troubles is the problem that DOC's that build up in your tank are toxic to the fish, shutting down metabolic pathways. So even if this worked (it won't btw) you would rid your tank of excess nitrates but not of excess DOC, and you just added more DOC to your tank in the form of Vodka (a fantastic preservative for all the fish you are about to kill too!!!) DOC levels are not readily tested for in home aquaria as the tests for them are complex, expensive and of poor accuracy. The best way to test for them is to measure the nitrates and know that if the nitrates are high, so are your DOC's.
Live plants btw do a great job of using up nitrates (but not DOC's) and can lower your levels for you. Even stuffing a spider plant "spider" into the top of an HOB filter will help lower nitrates, but you would still need to lower the level so f DOC's with a water change. Or you could..... CHANGE THE WATER IN YOUR TANK!
If you don't want to change the water in your tank, keep pet rocks. Its part of owning fish.