When evaporation occurs, it causes the contaminants present in the water to concentrate. When you top off the tank, you merely redilute the contaminants, not remove them. So, topping off a tank is in no way synonymous with a water change. Most of us will perform wcs to keep the concentration of nitrates and phosphates in check. In this sense, nitrates and phosphates act as a barometer of general water quality. However, the nitrates and phosphates are by no means the only contaminants which are accumulating. An aquarium is a CLOSED biological system and as such, will accumulate every conceivable organic and inorganic biproduct associated with biological activity. For example, the bacteria within the biofilter are in a constant state of turnover. When they die, they disintegrate and discharge their internal contents into the water. Some of this material is recycled by other bacteria...but some is not. All living creatures will discharge a variety of organic acids into the environment. If you combine this with the CO2 being discharged by both the fish and the aerobic bacteria (CO2+H2O=carbonic acid), this closed system will often acidify very quickly. This means that routine wcs are also required to reestablish a working KH within the tank. The accumulation of soluble organic contaminants within an aquarium is not well documented because it is complex and variable. However, I can assure you that it is occurring and will have an injurious effect upon the health of your fish.