methane? naaaaaaw
Hydrogen sulfide is the gas your looking for
taken from wikipedia
Hydrogen sulfide (hydrogen sulphide in British English), H2S, is a colorless, toxic, flammable gas that is responsible for the foul odor of rotten eggs and flatulence. It often results when bacteria break down organic matter in the absence of oxygen, such as in swamps, and sewers (alongside the process of anaerobic digestion). It also occurs in volcanic gases, natural gas and some well waters.
They CAN create these gases with the addition of organic matter ( think substrate clogged with fish ****!!)
the medium must be anaerobic and clean if you just want to have nitrogen gas as the product.