Even with the existing stock moving over I wouldn't add anything right away and try and feed lightly for a couple of weeks.
The old tank, decor, and substrate all are part of the bio filter. BB colonizes on those surfaces just like it does on the bio media. If your using the same color substrate I would add all your old substrate into the 300 along with the new stuff. It will help speed things up.
Pics man pics
Also if can pick up some tetra safestart plus. It's bb in a bottle you can quickly cycle a tank with it but to use that to cycle a 300 from scratch would be really expensive especially with the bioload those beasts put out.
What's the plan for the old tank ?