WS by itself would be fine for waterproofing but I want the interior to be black when I'm done (one of the reasons I didn't go with LR/Pond Coat). You can tint the WS epoxy but it just makes it darker, not black (you can still see the wood grain underneath).
Based on the WS manual it's fine to put a topcoat over the cured WS epoxy. Sweetwater would probably have been the easiest to apply but this was not an option for me because of the toxicity and smell (I'm building this in the middle of my small, poorly ventilated apartment). Pond Shield was the only other black two part epoxy I could think of as a top coat. Plus it was available locally from a nearby pond place.
I contacted Butch at Pond Armor and he said that Pond Shield could be applied over WS epoxy as long as it was sanded with 60grit sandpaper first. The PS may have been fine as a standalone product but since I don't have any external framing on the tank I didn't want to take any chances so I decided to incorporate some fiberglass, and the WS epoxy is so much better for wetting out cloth than the thick PS. Probably overkill, but since my test fill is going to be in the middle of my living room I'd rather do this right the first time rather than have to deal with leaks.