Unfortunately clear acrylic and polycarbonate look pretty much the same. I'm in the plastics recycling industry and due to the tons and tons of scrap we receive on a daily basis, including sheet polycarbonate and acrylic, sometimes mixed within a skip, it is important to be able to identify different types of plastics and quick. We have infra red spectrometers to analyse the ones we're not sure of but by and large the best method that I use out in the yard when skips turn up is to burn a piece, just a corner of a piece with a cigarette lighter tells me exactly what it is.
This is the test that truly gives the game away because they burn totally different.
Acrylic will burn with a faint flame. When you take the lighter away the flame will self extinguish and the surface of the burnt area will bubble. The smell is very sweet.
Polycarbonate on the other hand, the flame will flicker. It too will self extinguish when you take the lighter away and the smell is acrid. Also you will see a black crust appear where the plastic was burning.
You don't need to go mad with the lighter, just a tiny corner area will suffice.