My main concern with this build is the bottom. Theoretically, it could work using the two existing bottom panes joined with silicone (and obviously has before with the pic of the one joined lengthwise earlier in this thread), but I'm not sure I'd trust silicone alone that way. I noticed though that you're planning on buying a new piece of glass as the bottom pane, in which case my only concern is moot. Of course, buying that pane of 48" x 48" glass that's about 3/8" tempered glass would probably by itself justify just buying a new tank as it'll probably cost about $100 on its own.
All that being said, if you're going to do it anyway with either a new pane of glass for the bottom, or just butting the two bottom pieces together, why not just take a long pane from each of the two 55s off, and all side panes from both tanks? That way, you could use all four long panels with no joins in the middle on any of the four sides? As said previously, you'd have to brace it both front to back AND side to side, but you'll have to do that anyway even if you butt the two shorter pieces together for each of the two sides. As for the water pressure and glass thickness, that's a non-issue here as it's not changing in this build.