Getting rid of nitrates

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Howdy,

Miles said:
Good info

Thank you.



Miles said:
Are you basing all of your chemical knowledge on what's fact in the 'agriculture' world? Perhaps growing plants under water is different?

No. and No. And I am not a farmer, if you mean that :) Liebig's Law is universal. The limiting factor determines the growth. In agriculture, that is nitrate. In rivers, in our climate and geology, that's mostly phosphate (thus, my example with the detergents).


Miles said:
they both agreed the 'less nitrate' effect you see is often plants eating ammonia/nitrite in different stages. I also see this in some books.

Your friends and the books you refer to may be somewhat misleading or simply wrong. Plants indeed can use nitrite and ammonia, but no fish survive at concentrations high enough for plants to use nitrite or ammonia as significant nitrogen sources. For all practical purposes, neither nitrite nor ammonia play any role as plant nutrient in our hobby. What you refer to as "less nitrate effect" is merely based on plants using nitrate as nutrient. Has nothing to do with nitrite or ammonia.



Miles said:
I have never had an Ammonia spike on the planted system, even when I add a ton of fish to it. The Nitrates seem to never get really low

I assume you never had an ammonia or nitrite peak because your system is well established. You have a high enough capacity of bacteria to gobble it all up to form nitrate. And high nitrate levels with either plenty of fish or big fish are not surprising.


Miles said:
With the high nitrates in my tanks, why would I have huge bundles of Hornwart die off? Lack of Nutrient balance I am assuming? I was told it was the lack of the ammonia being present in the water, because plants need a make-up of all 3 components to thrive.

You already said it: Lack of other nutrients. Or - and this also is one of the factors in Liebig's Law - light. Depending on your light source, you have to change lamps every so often. That's about 6-12 months for regular fluorescent lights, 12-24 months for compact fluorescent and longer for metal halide. Also, the type of lamp is important, plants need the right spectrum. Ergo: A shop light from Home Depot is fine for fish only, but it might cause big trouble with some plants. You mentioned that swords grow but hornwart doesn't. Different species have different requirements, to the nutrients and to the light. As a matter of fact, swords are pretty easy with light. I have one growing under a light bulb :WHOA: Hornwart seems to have different requirements. Apparently, there is another limiting facor there for it, as said, most likely the lighting. It cannot be nitrates. You seem to have plenty of those ;)



Miles said:
Interesting there are very little river systems in the wild that have Nitrates in the water, yet plants still grow abundantly.

In those systems, nitrates occur at a concentration that is enough but not too much for the plants. I.e. nitrates get used right away and do not accumulate in free water.


Miles said:
Many of the reefkeepers I have talked to agree that the vegetation 'Calurpa' in a SW tank needs a steady flow of Ammona/Ni/Na to stay healthy, or it will die off. I have witnessed this happen first hand in my tank. I held off feeding my tank for a week, and my entire bunch of plants died off, even though Nitrates in the SW tank were at a steady 20-40ppm.

I am surprised that those reefkeepers still have fish. Honestly, they are not good hobbyists if they cannot run a tank without nitrate and/or ammonia. As a matter of fact, Calurpa growns in a basic (high pH) environment. The acid/base equilibrium between NH4+ and NH3 would be completely shifted to NH3. Your tank would smell, if not stink like ammonia, if that was in high enough concentrations to be used as nitrogen source by plants. Fish would have long been dead.

You quit feeding for a week. You had plenty of nitrates in there. Thus, nitrates cannot be the limiting factor. As stated before, they rarely are in our hobby. Quite the opposite: We tend to have too much of them. The reason is that our fish density and food are higher than in the wild. Anyhow, I assume it was another nutrient, which your tank lacked. Looks like you added just enough by feed or just enough got converted by your fish (i.e. pooped out) that your Calurpa was fine. Once that source dried out, the plants could not sustain. That especially applies to algae. And Calurpa is an algae. They have no depots for bridging a period of famine. That's why you can get rid of algea by turning the lights off and covering your tank for three days. Macrophytes (higher plants) survive just fine. Algae starve to death since they don't have any depot on nutrients nor can they generate any since photosynthesis won't work in the dark..
FYI: In the natural habitat of Calurpa, no low-valent nitrogen compounds (i.e. nitrite, ammonia) can be detected in the water. And that is not because they use it up too fast ;)


Miles said:
I am going to have to take this discussion to a forum with a bunch of planted tank buffs ;)


If it's the same guys as the reef keepers you mentioned above, then stay away from them :screwy: ;)


Peace out,

HarleyK
 
Is this the same calurpa that is being outlawed because of what is happening in the Meditteranian?sp?
 
Yup, same beast.

Any tank with fish is constantly producing ammonia and any tank with good biological filtration is also producing nitrite and nitrate. Facts of fish-keeping life. It would seem to me that plants could use any concentation of these compounds, though not exclusively one or the other.

Laura
 
You could always use Nitra-Zorb, or Chemi-Pure they both do the job.
 
Stella said:
It would seem to me that plants could use any concentation of these compounds, though not exclusively one or the other.Laura

Howdy,

That's right. But in a functioning tank, with biological filtration, there is hardly any (or no) nitrite or ammonia. If there is, then the plants can use some up, but nitrate still remains their main nitrogen source, and they can live just fine with only one nitrogen source, i.e. nitrate.

Let me emphasize it again: If you have detectable levels of nitrite in your water, fish die. Nitrite is toxic above 0.2 mg/l, lethal at 1.6 mg/l. In a functioning biofilter, a) nitrite is formed at a very slow rate and b) the nitrite that has formed is immediately oxidized to nitrate by bacteria. The same for ammonia. It is toxic above 0.25 mg/l, depending on the pH value.

I.e. for both: As soon as you can detect it, it causes harm. And plants can't save your fish from nitrite nor ammonia poisoning.

HarleyK
 
Miles said:
From what I understand, removing Nitrates is near impossible..

Heres what I have picked up over the years..

The large display tanks found in Las Vegas casinos, do not do ANY water changes.. They have huge sand filters, which somehow have a source of bacteria that actually breaks down nitrates. I have no physical evidence of why or how this happens, but I understand they never change the water, and the nitrates sits at around 200ppm at all times..

Nitrates are used VERY little by plants, but infact it is Ammonia/Nitrite that is consumed by plants in the prior stages of the nitrogen cycle. Some plants and algaes do use more Nitrates than others, but the 'less nitrate' effect that most people see in a planted aquarium, is the ammonia/nitrite being consumed in an earlier stage.

Chemicals can be used to chemically 'bind' Nitrates, Nitrite and Ammonia. These are sulfur based chemicals, such as AmQuel and Prime. Keep in mind, They are just 'locking' the Nitrates into a less harmful substance, and not actually removing them. So when you chemically bind your Nitrates, that leaves less 'clean' water open to saturate the new incoming nitrates, thus leading to a higher concentrate of both regular nitrates and chemically binded nitrates.

Sulfur Reactors, often used by large public aquariums. Even though they are not very reasonable for a domestic usage, I have seen some people who have learned and installed these into their large home tanks. They are huge reactors (look like calcium reactors for SW), that are full of sulfur.. The water slowly flows through the sulfur, and it chemically binds the Nitrates within the sulfur, not allowing them to be released into the tank (Like AmQuel).. Eventually the Sulfur will become exhausted, as it's effect is very similiar to zeolite with ammonia. The problem with these is when doing maintenance, if you happen to do anything incorrectly or leach any contents of the sulfur reactors into the main system, you could poison the entire tank.

I have seen a few other 'miracle' filtration systems like the Aqualizer and other misc gadgets, but I think it's all speculation. This bakki shower sounds very interesting, as I would like to hear more about it. I am starting to believe there is a bacteria that does eat/breakdown nitrates, but it's very hard to harbor this bacteria and keep it alive. Perhaps the massive sand filters that are operated on such a huge scale, have enough oxygenation and surface area to generate this 'de-nitrate' bacteria, but I have no clue. I would love to hear more scientific reports on the matter..

I would go with a planted refugium, if I were you.. It's inexpensive and cost-effective, and if done properly it could also be functional as a grow out tank or display tank. I have pictures of how to create one, and would be willing to help you with any ideas..

Hope that helps,

Miles

bro they use wat we call DSB (deep SEa Bed)....bvecause of low levels of oxygen, oxygen ius depleted thus promoting anerobic bacteria..thud nitrate break down............

plants can take nitrate too, however will prefer ammonia/nitrite...the eliminiation of ammonia/nitrite will elimnainate nitrate as well
 
Its possible to make a simple DIY Denitrator, I only posted about this a couple of weeks ago:

http://www.monsterfishkeepers.com/forums/showthread.php?t=8319

You just need to somehow house anearobic bacteria - (ie. run O2 depleted water through some biological filter media).

Here are some basic plans for one: http://www.aloha.net/~hqf/indexdondenitrator.htm

There was a thread on Arofanatics which discusses it in depth, there were a heap of those guys building them out of PVC pipe and very long lengths of airline tubing.

Been thinking of making one myself once I get a few other projects out of the way!
 
sohfatfish said:
Maybe you want to try out bakki showers with bacteria house as the media if you have the money. It supposedly reduces nitrate, raises water quality and a whole host of other stuff. Momotaro Koi farm is the inventer of these bakki showers and bacteria house and they claim that their water has 0 nitrate without the use of any other media.
Expensive!!!
 
this is a cop out and a pretty obvious answer. . water changes are the best way of removing nitrates in the tank. Why use chemicals when a simple water change is all it takes? I understand if its an emergency but its all about doing regular maintenance .
 
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