++ to the posts above. Drain water-- then add dechlorinator-- then fill tank. Or add dechlorinator as you fill ok too.
There's just no reason to fill your tank with chlorinated water, then add dechlorinator, unless you're just trying to prove a point that won't change anyone's mind anyway. It's playing Russian roulette with your fish. There are some scenarios under which you might get away with it-- for example, your water has chlorine, not chloramine and the water travels far enough before reaching your fish that most of the chlorine dissipates. But all it would take in that scenario is a change to chloramine or for your municipality to add an increased dose of chlorine or chloramine, whether by mistake or to correct an issue they're dealing with-- either of which can happen-- and there goes any margin of error you might have skated by on to that point.
There are a lot of things in fishkeeping that I chalk up to one way is more or less as good as another and it comes down to personal preference, but this isn't one of them.
There's just no reason to fill your tank with chlorinated water, then add dechlorinator, unless you're just trying to prove a point that won't change anyone's mind anyway. It's playing Russian roulette with your fish. There are some scenarios under which you might get away with it-- for example, your water has chlorine, not chloramine and the water travels far enough before reaching your fish that most of the chlorine dissipates. But all it would take in that scenario is a change to chloramine or for your municipality to add an increased dose of chlorine or chloramine, whether by mistake or to correct an issue they're dealing with-- either of which can happen-- and there goes any margin of error you might have skated by on to that point.
There are a lot of things in fishkeeping that I chalk up to one way is more or less as good as another and it comes down to personal preference, but this isn't one of them.