I saw mention that you were going to heavily brace it... I'm not sure how you're planning to do that, but you'll definitely need to: OSB (pressboard as you call it locally I guess) is not very stiff. The other thing to keep in mind is that since you're not using polyester resin anymore, your back will not be sealed, so spilled/splashed/condensed water will be a problem to consider. Your front structure should also be braced quite a bit - that 3" strip of OSB will not be enough to support the window IMO.
Just some other general comments in response to some ideas I saw in this thread:
1) Epoxy and polyester are NOT compatible materials. Epoxy will form a weak bond with cured polyester, but polyester will not cure in the presence of epoxy, so mixing the two is a no-no.
2) Kitty hair is a ***** to work with, and is designed for filling large voids more than being a structural element - it has a lot of low strength fillers and thickeners in it along with the fiberglass strands. If one wanted a pasty putty to put in corners, you'd be better off buying chopped strand and mixing it with resin directly. This mix would go down BEFORE the fiberglass cloth/mat so the mat would have a nice radiused corner to lay in.