Canister filters do not need less maintenance than HOBs, unless you use a prefilter. In this case the prefilter will need frequent maintenance but you can let the canister itself run for much longer between cleanings.
What is your intended stocking for the tank? Your existing filtration may be sufficient. Also consider the possibility of a sump (under-tank) filter. These combine the flexibility and easy maintenance of HOBs with the low visibility of canisters. Premade sumps are a bit expensive, but it is cheap and easy to make your own; there are plenty of threads on DIY sumps in the DIY subforum.
Canister/HOB combos are fine and many hobbyists use them. Having multiple filters is a good idea, as it gives you backup in case one fails, and also allows you to dedicate different filters to different things. For example, since pristine water is important to you, you could dedicate one HOB to fine mechanical filtering, with lots of very fine media, and leave the canisters and other HOBs with coarser media for general biological and mechanical filtration. You would then need to do frequent maintenance on that one filter but could let the others run longer.
You mentioned the UV filters in the canisters you wish to buy. UV filters are fine and well, but really shouldn't be necessary unless you have a green water or pathogen outbreak; the rest of the time they are just wasting power, restricting flow, and cutting down the lifespan of expensive UV bulbs. I think of them like medication: only use when necessary.