When it first starts raining, any water collected will have impurities from the air in it. After a period of rainfall, the impurities in the air are washed away, and the water is then safe for aquarium use. So basically, wait until it rains for a bit before starting to collect the rainwater. Also be aware that most rainfall in the US is acidic. It can lower your pH. You may want to add some baking soda to your pond after a rainfall.