Oy what a week. here is the upshot.
I messed up my bio-farm cycling. It looked like it was going OK and then it stalled. I added some Baking soda and did a WC when the temp went into the low 90s and that seemed to make things OK. Last week I added ammonium chloride for about 5 ppm and it stalled. I did a water change and when it moved again I redosed to 5 ppm and it stalled and was for about 3 days.
I have to admit up front I got too cocky and assumed if I did it, it would work. But the number of filters was high and I have usually managed fine just testing for ammonia after it is added. So I did no other tests. Today I came to my senses and decided to test for KH. 1 drop turned it yellow on my API kit. Very bad fir cycling if accurate. But the kit was very old, so I decided to test for pH. I used the regular range API kit. It read at the very bottom of the scale- 6.0. That confirmed there was likely a KH issue which dropped the pH. I then dosed 1 tsp. of baking soda into the 35 or so gals. I waited a bit and retested for pH- 7.2+.
To raise the KH without raising the GH, add sodium bicarbonate (NaHCO3), commonly known as baking soda. 1/2 teaspoon per 100 Liters {26.4 gal} raises the KH by about 1 dH. Sodium bicarbonate drives the pH towards an equilibrium value of 8.2.
However, testing for KH it still was 1 drop. Considering I had clouded the water from waving the crushed coral bag in the water as well as adding the Sodium bicarb, the KH should have read higher. So I assumed the kit was bad from age. The local PetCo was out of them.
Here is what had to have happened by my being so cocky and not testing. As the bacteria processed ammonia. They used up the carbonates/bicarbonates. The bag of crushed coral could not dissolve fast enough and the KH dropped. This in turn allowed the acid from the cycle to drop the pH. When the pH is at the 6.0 level in 86F water and it has 5 ppm of Total Ammonia, only 0.0043 ppm is NH3, 4.9957 pp, in NH4.
Many of the ammonia bacteria in tanks prefer NH3 and have receptors for that. they may have some for NH4 as well. Other bacteria will have more NH4 receptors but may not process that as effectively as the ones using NH3 can.
So what I did was to allow the ammonia in the tank to become mostly NH4 and this slowed things way down. I let my hubris overcome my knowledge-
call me Homer, DOH!
Ain't fish keeping fun........
I suppose I should test nitrite and even nitrate, but those are old kits too. *sigh*
In my defense I must say that this is the largest number of filters for the most gallons I have tried to cycle from scratch in one smallish tank. I have never tried to go as fast either. It was the wrong time to get cocky......
Here is the new plan:
1. Change about 50% water daily. 30 minutes after refiling the tank, test for ammonia. Add enough ammonium chloride to reach 4-5 ppm.
2. Check the pH after the refill and add sodium bicarb as needed to keep KH and pH up. Add more crushed coral to the bag as needed or add a second bag.
3. By the end of the weekend i should have at least 3 of the other 5 tanks cleaned and set-up for fish. 3 are already cleaned and have the backs and sides wuth black backgrounds. They just need to be filled and set up with wood and some rocks/slate and maybe some sand. I have heaters and therms for them.
4. Once a new tank is up to temp, I will move it's filters from the bio-farm into it. I expect mone of the filters will be fully cycled yet. I will continue cycling in two Poret cubes in the new tanks as well as thiose still in the bio-farm. I should not have issues with KH/pH etc. in the new tanks and they will alleviate the issues in the bio-farm by reducing the needed concentration of ammonia going in.
5. Order a new GH/KH kit over the weekend. I just bought a back-up ammonia kit.
Now for some interesting news. Yesterday I was doing the weekly cleaning and water change on my Budrovcan line 236 grow tank and was surprised to spot several newly free swimming fry. I have not added any of these sized fish to that tank in about 8 months. This means the oldest six fish in that tank must be a spawning group. This is not really what I needed to see as I am trying to downsize big-time not go in the other direction.