Nope. It would be too small a tank for a Red Devil.can a red devil live a comfortable life in a 75 gallon? Thanks!
Plecos are usually ignored, so can be kept with most fish, including aggressive cichlids. Plecos have armored bodies, so usually don't take damage when the cichlid occasionally pick on them. Just provide them a hiding place (wood, rocks) etc to hide if the cichlid gets too aggressive and they should be fine.Is it possible to keep a pleco or catfish with any of these
Lastly, all cichlids are interactive and fun fish. Hyper aggressive cichlids make your job more difficult as they may even bite your hand when your trying to clean the tank and those bites hurt and some are known to jump out of the tank looking to bite the owners hand.
Simply put whichever cichlid you choose, will get used to you and will come begging for food as well as chasing you to the front of the tank. Cichlids in general have a lot of personality, which is what makes them so popular in the hobby.
My suggestion is since you are new to the hobby, pick a semi aggressive fish that doesn't grow too large (pick a cichlid whose looks you like), rather than a hyper aggressive fish. It will make your job of cleaning the tank a lot more easier and will also give you a few option as you may be able to add tank mates for semi aggressive species.