If you feel you must cool the water...and I, like many here, don't feel it's essential...then increased aeration, a fan blowing across the water surface, and keeping the tank uncovered will all increase the rate of evaporation and thus cool the water slightly.
If you have a submersible pump in your system, as
T
Tj203
noted, you must consider that it is water cooled and is therefore heating your water slightly. Usually not a concern, but at least be aware of it. Also, how are you measuring your temps? Digital thermometers are usually pretty accurate, but if either or both of your thermometers are the stone-age glass-tube-with-red-fluid type, they can easily be off by several degrees. The tanks might actually be the same temp. (edited to add: just read your last post, so unlikely that the thermometers are the issue here, but something to be aware of nevertheless...after all, in the picture I can see at least one Fred Flintstone thermometer and they just can't be trusted...
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Finally...relax! Drain most of the water from the small tank, and place that water into the larger. Move the fish immediately, directly from one tank to the other, no buckets required. They are staying in the same water at the same temp, so no shock or stress beyond that of being netted; in fact, best to simply pick up the pleco rather than netting as they tend to get stuck in nets due to their spines.
Now that they are in their new home, start adding water of the same temperature to fill that tank. Let's say that you are able to get 30 gallons of water from the old tank to the new. Topping up that tank now with freshly treated, temp-matched water will probably take another 70 or 80 gallons, which means that you have essentially performed a roughly 60-70% water change for your fish. They will love it!
If this tank does indeed rise back up a couple degrees after you do all this, it will take hours. 80 degrees might not be ideal for either goldfish or plecos, but shouldn't stress them unduly on a temporary basis until the hot weather subsides. Right now you seem to be suffering more from stress than they will throughout the whole procedure. Good luck, relax, and enjoy your new tank .